Fenton Redox Chemistry: Arsenite Oxidation by Metallic Surfaces

Fenton Redox Chemistry: Arsenite Oxidation by Metallic Surfaces

Borges Freitas, S.C.
Van Halem, D.
Badruzzaman, A.B.M.
Van der Meer, W.G.J.

Civil Engineering and Geosciences

Water Management

2014-09-21

Pre-oxidation of As(III) is necessary in arsenic removal processes in order to increase its efficiency. Therefore, the Fenton Redox Chemistry is defined by catalytic activation of H2O2 and currently common used for its redox oxidative properties. In this study the effect of H2O2 production catalysed by O2 in metallic surfaces (MS), such as metallic Cu/Zn alloys and Composite Iron Matrix (CIM), for As(III) oxidation is under investigation. Preliminary results show that As(III) is partly oxidized only by the presence of O2 without addition of MS. However, with delayed addition of MS, As(III) oxidation occurred but only due to ROS catalyzed by the metallic surfaces.

As(III) oxidation
Fenton
Metallic Surfaces
Reactive Oxygen Species

http://resolver.tudelft.nl/uuid:009f2702-3cc2-4a7d-aabe-e871a0440816

IWA 2014: IWA World Water Congress and Exhibition "Shaping our Water Future", Lisbon, Portugal, 21-26 September 2014

Institutional Repository

conference paper

(c) 2014 The Author(s)