Print Email Facebook Twitter Deazaflavins as photocatalysts for the direct reductive regeneration of flavoenzymes Title Deazaflavins as photocatalysts for the direct reductive regeneration of flavoenzymes Author van Schie, M.M.C.H. (TU Delft BT/Biocatalysis) Younes, S.H.H. (TU Delft BT/Biocatalysis; Sohag University) Rauch, M.C.R. (TU Delft BT/Biocatalysis) Pesic, M. (TU Delft BT/Biocatalysis) Paul, C.E. (Wageningen University & Research) Arends, I.W.C.E. (TU Delft BT/Biotechnologie) Hollmann, F. (TU Delft BT/Biocatalysis) Department BT/Biotechnologie Date 2018 Abstract Deazaflavins are potentially useful redox mediators for the direct, nicotinamide-independent regeneration of oxidoreductases. Especially the O2-stability of their reduced forms have attracted significant interest for the regeneration of monooxygenases. In this contribution we further investigate the photochemical properties of deazaflavins and investigate the scope and limitations of deazaflavin-based photoenzymatic reaction systems. Subject BiocatalysisFlavinOld yellow enzymeOxygen dilemmaPhotochemistry To reference this document use: http://resolver.tudelft.nl/uuid:1f86906d-bc84-4e46-b021-216f78618aed DOI https://doi.org/10.1016/j.mcat.2018.04.015 Embargo date 2018-10-27 ISSN 2468-8231 Source Molecular Catalysis, 452, 277-283 Bibliographical note Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. Part of collection Institutional Repository Document type journal article Rights © 2018 M.M.C.H. van Schie, S.H.H. Younes, M.C.R. Rauch, M. Pesic, C.E. Paul, I.W.C.E. Arends, F. Hollmann Files PDF 1_s2.0_S2468823118301469_main.pdf 1.32 MB Close viewer /islandora/object/uuid:1f86906d-bc84-4e46-b021-216f78618aed/datastream/OBJ/view