Print Email Facebook Twitter Metal-organic and covalent organic frameworks as single-site catalysts Title Metal-organic and covalent organic frameworks as single-site catalysts Author Rogge, S.M.J. (Universiteit Gent) Bavykina, A.V. (TU Delft ChemE/Catalysis Engineering) Hajek, Julianna (Universiteit Gent) Garcia, H (Universitat Politécnica de Valencia) Olivos Suarez, A.I. (TU Delft ChemE/Catalysis Engineering) Sepúlveda-Escribano, A. (University of Alicante) Vimont, A. (ENSICAEN Ecole Nationale Superieure d'Ingenieurs de Caen) Clet, G (ENSICAEN Ecole Nationale Superieure d'Ingenieurs de Caen) Bazin, P. (ENSICAEN Ecole Nationale Superieure d'Ingenieurs de Caen) Kapteijn, F. (TU Delft ChemE/Catalysis Engineering) Daturi, Marco (ENSICAEN Ecole Nationale Superieure d'Ingenieurs de Caen) Ramos-Fernandez, E.V. (University of Alicante) Llabres i Xamena, FX (Universitat Politécnica de Valencia) Van Speybroeck, V (Universiteit Gent) Gascon, Jorge (TU Delft ChemE/Catalysis Engineering) Date 2017-03 Abstract Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions. To reference this document use: http://resolver.tudelft.nl/uuid:34336b0d-bccc-4ab7-9ab0-21b79acc66bd DOI https://doi.org/10.1039/C7CS00033B ISSN 0306-0012 Source Chemical Society Reviews Part of collection Institutional Repository Document type journal article Rights © 2017 S.M.J. Rogge, A.V. Bavykina, Julianna Hajek, H Garcia, A.I. Olivos Suarez, A. Sepúlveda-Escribano, A. Vimont, G Clet, P. Bazin, F. Kapteijn, Marco Daturi, E.V. Ramos-Fernandez, FX Llabres i Xamena, V Van Speybroeck, Jorge Gascon Files PDF c7cs00033b.pdf 8.15 MB Close viewer /islandora/object/uuid:34336b0d-bccc-4ab7-9ab0-21b79acc66bd/datastream/OBJ/view