Print Email Facebook Twitter Manufacture of dense CAU-10-H coatings for application in adsorption driven heat pumps: Optimization and characterization Title Manufacture of dense CAU-10-H coatings for application in adsorption driven heat pumps: Optimization and characterization Author De Lange, M.F. Zeng, T. Vlugt, T.J.H. Gascon, J. Kapteijn, F. Faculty Mechanical Maritime and Materials Engineering Department Process and Energy Date 2015-05-12 Abstract CAU-10-H displays a highly suitable step-wise water adsorption behaviour for application in adsorption driven heat pumps and chillers. For actual application, manufacturing of coatings of this material on thermally conductive surfaces is highly desired. Direct, single-step, crystallization of CAU-10-H on either metallic or anodized aluminium yields a significant amount of by-product(s) and an inhomogeneous substrate coverage. Although adequate pretreatment of the substrates before crystallization improves the quality of obtained coatings, significant improvements are achieved only when crystal nucleation and growth are separated. More specifically, application of a reactive seeding approach with anodized aluminium leads to full coverage of the substrate surface, high MOF loading and high purity of the crystalline phase, homogeneous layer thickness, narrow crystal size distribution, and good stability in repeated water adsorption–desorption cycles. Subject Gold for GoldOpen Access To reference this document use: http://resolver.tudelft.nl/uuid:39500557-79e6-4cb6-9f7e-f6e28baece71 DOI https://doi.org/10.1039/C5CE00789E Publisher RSC Publishing ISSN 1466-8033 Source CrystEngComm, 2015,17 Part of collection Institutional Repository Document type journal article Rights (c) 2015 RSC Files PDF c5ce00789e.pdf 5.2 MB Close viewer /islandora/object/uuid:39500557-79e6-4cb6-9f7e-f6e28baece71/datastream/OBJ/view