Effect of type-III Anti-Freeze Proteins (AFPs) on CO₂ hydrate formation rate

Effect of type-III Anti-Freeze Proteins (AFPs) on CO₂ hydrate formation rate

Zhou, H. (TU Delft Engineering Thermodynamics)
Infante Ferreira, C.A. (TU Delft Engineering Thermodynamics)

2017

CO2 hydrate slurry is a favourable direct coolant of fresh products due to its large latent heat and phase change temperature around 7 °C. Continuous production of this slurry is, however, difficult to realise due to the high rate of hydrate formation. The use of additives is proposed with the purpose of decreasing the formation rate so that the controllability of the process is improved. Type-III Antifreeze Proteins (AFPs) are non-poisonous additives which, at low dosage, have proven to be efficient limiters of gas hydrate formation. The effect of these additives on the CO2 hydrate formation rate is experimentally investigated in this study.

The concentration of the AFPs investigated in this research is 10 ppm. Experimental results show that the supercooling degree of the solution is only slightly affected by the addition of AFPs. Results also show that the addition of AFPs slows down the dissolution rate of CO2 gas into the aqueous solution which is the first step of gas hydrate formation. A hydrate growth equation has been used, from which the experimental mass transfer coefficient of CO2 through the solution has been derived. Results show that the decrease of hydrate growth rate with the addition of AFPs can be related to a decrease of the CO2 mass transfer coefficient which gives a lower mass transport rate from bulk liquid phase to the crystal interface.

CO2 hydrate
Anti-Freeze Proteins (AFPs)
Growth rate
Mass transfer

http://resolver.tudelft.nl/uuid:636d9647-2229-4aa9-b246-0bba3c335dde

https://doi.org/10.1016/j.ces.2017.03.060

2019-04-05

0009-2509

Chemical Engineering Science, 167, 42-53

Accepted Author Manuscript

Institutional Repository

journal article

© 2017 H. Zhou, C.A. Infante Ferreira