Print Email Facebook Twitter Facile manufacture of porous organic framework membranes for precombustion CO2 capture Title Facile manufacture of porous organic framework membranes for precombustion CO2 capture Author Shan, M. (TU Delft ChemE/Catalysis Engineering; TU Delft ChemE/Transport Phenomena) Liu, X. (TU Delft ChemE/Catalysis Engineering) Wang, X. (TU Delft ChemE/Catalysis Engineering) Yarulina, I. (TU Delft ChemE/Catalysis Engineering; King Abdullah University of Science and Technology) Seoane, Beatriz (TU Delft ChemE/Catalysis Engineering; Debye Institute) Kapteijn, F. (TU Delft ChemE/Catalysis Engineering) Gascon, Jorge (TU Delft ChemE/Catalysis Engineering; King Abdullah University of Science and Technology) Date 2018 Abstract The development of new membranes with high H2 separation performance under industrially relevant conditions (high temperatures and pressures) is of primary importance. For instance, these membranes may facilitate the implementation of energy-efficient precombustion CO2 capture or reduce energy intensity in other industrial processes such as ammonia synthesis. We report a facile synthetic protocol based on interfacial polymerization for the fabrication of supported benzimidazole-linked polymer membranes that display an unprecedented H2/CO2 selectivity (up to 40) at 423 K together with high-pressure resistance and long-term stability (>800 hours in the presence of water vapor). To reference this document use: http://resolver.tudelft.nl/uuid:808c97c4-675a-41f3-9032-15942514cb99 DOI https://doi.org/10.1126/sciadv.aau1698 ISSN 2375-2548 Source Science Advances, 4 (9) Part of collection Institutional Repository Document type journal article Rights © 2018 M. Shan, X. Liu, X. Wang, I. Yarulina, Beatriz Seoane, F. Kapteijn, Jorge Gascon Files PDF eaau1698.full.pdf 722.94 KB Close viewer /islandora/object/uuid:808c97c4-675a-41f3-9032-15942514cb99/datastream/OBJ/view