Print Email Facebook Twitter As(V) rejection by NF membranes using high temperature sources for drinking water production Title As(V) rejection by NF membranes using high temperature sources for drinking water production Author Gonzalez Rodriquez, B.J. (TU Delft Sanitary Engineering) Heijman, Sebastiaan (TU Delft Sanitary Engineering) Rietveld, L.C. (TU Delft Sanitary Engineering) van Halem, D. (TU Delft Sanitary Engineering) Date 2019 Abstract In Nicaragua, a Central American country, geothermally influenced waters are frequently found to be contaminated with arsenic (as As(V)). This study investigated the effect of high-temperatures (25–50 °C), as found in geothermally influenced source waters, on the rejection of monovalent H2AsO4 - and divalent HAsO4 2- species (at pH 6,7 and 8) during NF membrane filtration of a multi-component solution containing Cl- and HCO3 -. In this multi-component solution, As(V) rejection was found to be enhanced at higher temperatures, which was in contrast to the previous assumption that temperature increase would have a negative effect on As(V) rejection. Previous studies were conducted with deionized waters, where pore size expansion and decreased viscosity drove As(V) rejection; however, in the presence of other anions such as those utilized in this study, As(V) rejection was promoted at higher temperatures. The enhancement of As(V) rejection at high temperature was associated with the presence of HCO3 - and Cl-, which are considerably more permeable than both As(V) species. An additional advantage of the higher temperature was the lower feed pressure (down to 1.5 bar) needed to operate these NF membranes, compared to colder waters. The lower energy consumption in combination with the improvement in As(V) rejection at higher temperatures shows the potential application of this technology for efficient treatment of As(V) contaminated, geothermally influenced waters for decentralised, rural drinking water production, in As-affected countries such Nicaragua. Subject ArsenicDrinking waterGeothermal sourcesNanofiltrationNicaraguaTemperature To reference this document use: http://resolver.tudelft.nl/uuid:8a03389e-77f5-4efc-9e8d-28a7b9ac85c9 DOI https://doi.org/10.1016/j.gsd.2018.11.011 Embargo date 2019-05-22 Source Groundwater for Sustainable Development, 8, 198-204 Bibliographical note Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. Part of collection Institutional Repository Document type journal article Rights © 2019 B.J. Gonzalez Rodriquez, Sebastiaan Heijman, L.C. Rietveld, D. van Halem Files PDF 1_s2.0_S2352801X18300699_main.pdf 1.73 MB Close viewer /islandora/object/uuid:8a03389e-77f5-4efc-9e8d-28a7b9ac85c9/datastream/OBJ/view