Print Email Facebook Twitter Experimental Determination of a Single Atom Ground State Orbital through Hyperfine Anisotropy Title Experimental Determination of a Single Atom Ground State Orbital through Hyperfine Anisotropy Author Farinacci, L.S.M. (TU Delft QN/Otte Lab; Kavli institute of nanoscience Delft) Veldman, L.M. (TU Delft QN/Otte Lab; Kavli institute of nanoscience Delft) Willke, Philip (Karlsruhe Institut für Technologie) Otte, A. F. (TU Delft QN/Otte Lab; Kavli institute of nanoscience Delft) Date 2022 Abstract Historically, electron spin resonance (ESR) has provided excellent insight into the electronic, magnetic, and chemical structure of samples hosting spin centers. In particular, the hyperfine interaction between the electron and the nuclear spins yields valuable structural information about these centers. In recent years, the combination of ESR and scanning tunneling microscopy (ESR-STM) has allowed to acquire such information about individual spin centers of magnetic atoms bound atop a surface, while additionally providing spatial information about the binding site. Here, we conduct a full angle-dependent investigation of the hyperfine splitting for individual hydrogenated titanium atoms on MgO/Ag(001) by measurements in a vector magnetic field. We observe strong anisotropy in both the g factor and the hyperfine tensor. Combining the results of the hyperfine splitting with the symmetry properties of the binding site obtained from STM images and a basic point charge model allows us to predict the shape of the electronic ground state configuration of the titanium atom. Relying on experimental values only, this method paves the way for a new protocol for electronic structure analysis for spin centers on surfaces. Subject electron spin resonancehyperfine interactionmagnetic sensingscanning tunneling microscopysingle-atom magnetismvector magnetic field To reference this document use: http://resolver.tudelft.nl/uuid:8bc03a17-7bcd-44bf-b068-e714afbea8c8 DOI https://doi.org/10.1021/acs.nanolett.2c02783 ISSN 1530-6984 Source Nano Letters: a journal dedicated to nanoscience and nanotechnology, 22 (21), 8470-8474 Part of collection Institutional Repository Document type journal article Rights © 2022 L.S.M. Farinacci, L.M. Veldman, Philip Willke, A. F. Otte Files PDF acs.nanolett.2c02783.pdf 4.49 MB Close viewer /islandora/object/uuid:8bc03a17-7bcd-44bf-b068-e714afbea8c8/datastream/OBJ/view