Print Email Facebook Twitter Simulating Chiral Induced Spin Selectivity using Non-Equilibrium Green's Functions Title Simulating Chiral Induced Spin Selectivity using Non-Equilibrium Green's Functions Author Vroomans, Tim (TU Delft Applied Sciences) Contributor Thijssen, Jos (mentor) Degree granting institution Delft University of Technology Date 2019-01-30 Abstract In this thesis a method is proposed to improve upon the Non-Self-Consistent Green's function transport calculation used by the Amsterdam Density Functional package (ADF) made by Software for Chemistry and Materials (SCM) so ADF is able to simulate Chiral Induced Spin Selectivity (CISS). CISS is an effect that causes spin polarisation to occur in currents that flow through chiral molecules, such as DNA. In this thesis, Helicene is chosen since it has a helical structure but it is also a relatively simple molecule to simulate. In the calculations the helicene is attached to two gold contacts via a sulfur atom on each side. Gold is chosen for its strong spin-orbit coupling, which is thought to cause the effect. The native Green's function transport calculation uncouples the spin-orbitals into their two spin directions, it essentially preforms the same calculation twice for both spin direction. Because the spin directions are treated separately this method neglects any interactions between electrons of different spin. Therefore no spin polarisation will arise in the absence of a magnetic field. The proposed method improves on this by accounting for the full spin-orbitals, and therefore their potential overlap with each other. Because the potential interactions between orbitals occupied by electrons of different spin, spin-flip interactions are taken into account in the Green's function when calculating the transmission of the Helicene. This then gives rise to potential spin polarisation in the current. Due to a lack of time and an overabundance of run-time errors in the FORTRAN code used to implement the proposed method in ADF 2019, no results could be obtained to confirm or deny this. To reference this document use: http://resolver.tudelft.nl/uuid:961b8e1c-fd80-43aa-a17b-925e173ec6c7 Part of collection Student theses Document type bachelor thesis Rights © 2019 Tim Vroomans Files PDF BEP_Thesis_Tim_Vroomans.pdf 2.77 MB Close viewer /islandora/object/uuid:961b8e1c-fd80-43aa-a17b-925e173ec6c7/datastream/OBJ/view