Print Email Facebook Twitter In Situ Characterization of the Reaction-Diffusion Behavior during the Gradient Interphase Formation of Polyetherimide with a High-Temperature Epoxy System Title In Situ Characterization of the Reaction-Diffusion Behavior during the Gradient Interphase Formation of Polyetherimide with a High-Temperature Epoxy System Author Zweifel, Lucian (University of Applied Sciences and Arts Northwestern Switzerland) Brauner, Christian (University of Applied Sciences and Arts Northwestern Switzerland) Teuwen, Julie J.E. (TU Delft Aerospace Manufacturing Technologies) Dransfeld, C.A. (TU Delft Aerospace Manufacturing Technologies) Date 2022 Abstract This study presents two novel methods for in situ characterization of the reaction-diffusion process during the co-curing of a polyetherimide thermoplastic interlayer with an epoxy-amine thermoset. The first method was based on hot stage experiments using a computer vision point tracker algorithm to detect and trace diffusion fronts, and the second method used space-and time-resolved Raman spectroscopy. Both approaches provided essential information, e.g., type of transport phenomena and diffusion rate. They can also be combined and serve to elucidate phenomena occurring during diffusion up to phase separation of the gradient interphase between the epoxy system and the thermoplastic. Accordingly, it was possible to distinguish reaction-diffusion mechanisms, describe the diffusivity of the present system and evaluate the usability of the above-mentioned methods. Subject CharacterizationInterphase formationOptical proper-ties/techniquesRaman spectroscopyReaction-diffusionThermoplasticThermoset resin To reference this document use: http://resolver.tudelft.nl/uuid:dbb8d5a8-a84e-48e3-8c47-27aa26878299 DOI https://doi.org/10.3390/polym14030435 ISSN 2073-4360 Source Polymers, 14 (3) Part of collection Institutional Repository Document type journal article Rights © 2022 Lucian Zweifel, Christian Brauner, Julie J.E. Teuwen, C.A. Dransfeld Files PDF polymers_14_00435_v3.pdf 1.91 MB Close viewer /islandora/object/uuid:dbb8d5a8-a84e-48e3-8c47-27aa26878299/datastream/OBJ/view