Print Email Facebook Twitter In Situ Spectroelectrochemical Determination of Energy Levels and Energy Level Offsets in Quantum-Dot Heterojunctions Title In Situ Spectroelectrochemical Determination of Energy Levels and Energy Level Offsets in Quantum-Dot Heterojunctions Author Boehme, S.C. (TU Delft ChemE/Opto-electronic Materials) Vanmaekelbergh, Daniël (Universiteit Utrecht) Evers, W.H. (TU Delft ChemE/Afdelingsbureau; Kavli institute of nanoscience Delft) Siebbeles, L.D.A. (TU Delft ChemE/Opto-electronic Materials) Houtepen, A.J. (TU Delft ChemE/Opto-electronic Materials) Date 2016-03-17 Abstract Charge transfer in semiconductor heterojunctions is largely governed by the offset in the energy levels of the constituent materials. Unfortunately, literature values for such energy level offsets vary widely and are usually based on energy levels of the individual materials rather than of actual heterojunctions. Here we present a new method to determine absolute energy levels and energy level offsets in situ for films containing CdSe and PbSe quantum dots. Using spectroelectrochemistry, we find a type I offset at the CdSe-PbSe heterojunction. Whereas the energy level offset follows the expected size-dependent trend, the absolute positions of the 1Se level in the individual CdSe or PbSe quantum dots does not. This level varies by more than 0.5 eV, depending on film composition and surface defect concentration. Rather than extrapolating energy level offsets from measurements on pure CdSe or PbSe quantum-dot films, we suggest measuring energy level offsets in heterojunctions in situ. To reference this document use: http://resolver.tudelft.nl/uuid:eb97947f-95b1-402a-ba3f-ac965f693135 DOI https://doi.org/10.1021/acs.jpcc.5b12016 ISSN 1932-7447 Source The Journal of Physical Chemistry C, 120 (9), 5164-5173 Part of collection Institutional Repository Document type journal article Rights © 2016 S.C. Boehme, Daniël Vanmaekelbergh, W.H. Evers, L.D.A. Siebbeles, A.J. Houtepen Files PDF acs.jpcc.5b12016.pdf 2.96 MB Close viewer /islandora/object/uuid:eb97947f-95b1-402a-ba3f-ac965f693135/datastream/OBJ/view