Print Email Facebook Twitter Effects of graphene defects on gas sensing properties towards NO 2 detection Title Effects of graphene defects on gas sensing properties towards NO 2 detection Author Ricciardella, F. (TU Delft Electronic Components, Technology and Materials) Vollebregt, S. (TU Delft Electronic Components, Technology and Materials) Polichetti, Tiziana (ENEA Research Center) Miscuglio, Mario (Italian Institute of Technology; University of Genova) Alfano, Brigida (ENEA Research Center; Università degli Studi di Napoli Federico II) Miglietta, Maria L (ENEA Research Center) Massera, Ettore (ENEA Research Center) Di Francia, Girolamo (ENEA Research Center) Sarro, Pasqualina M (TU Delft Electronic Components, Technology and Materials) Date 2017-04-05 Abstract The crystal structure of graphene flakes is expected to significantly affect their sensing properties. Here we report an experimental investigation on the crystalline structure of graphene aimed at exploring the effects on the gas sensing properties. The morphology of graphene, prepared via Chemical Vapor Deposition (CVD), Liquid Phase Exfoliation (LPE) and Mechanical Exfoliation (ME), is inspected through Raman spectroscopy, Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). CVD and LPE-graphene structures are found to be more defective with respect to ME-graphene. The defects are due to the jagged morphology of the films rather than originating from intrinsic disorder. The flatness of ME-graphene flakes, instead, explains the absence of defects. Chemiresistors based on the three different graphene preparation methods are subsequently exposed to NO2 in the concentration range 0.1–1.5 ppm (parts per million). The device performance is demonstrated to be strongly and unambiguously affected by the material structure: the less defective the material is, the higher the response rate is. In terms of signal variation, at 1.5 ppm, for instance, ME-graphene shows the highest value (5%) among the three materials. This study, comparing simultaneously graphene and sensors prepared via different routes, provides the first experimental evidence of the role played by the graphene level of defectiveness in the interaction with analytes. Moreover, these findings can pave the path for tailoring the sensor behavior as a function of graphene morphology. To reference this document use: http://resolver.tudelft.nl/uuid:f8e9af0d-12f1-451e-861e-61592ad0d074 DOI https://doi.org/10.1039/c7nr01120b ISSN 2040-3364 Source Nanoscale, 9 (18), 6085-6093 Part of collection Institutional Repository Document type journal article Rights © 2017 F. Ricciardella, S. Vollebregt, Tiziana Polichetti, Mario Miscuglio, Brigida Alfano, Maria L Miglietta, Ettore Massera, Girolamo Di Francia, Pasqualina M Sarro Files PDF c7nr01120b_1.pdf 3.31 MB Close viewer /islandora/object/uuid:f8e9af0d-12f1-451e-861e-61592ad0d074/datastream/OBJ/view