Print Email Facebook Twitter Onsager’s reciprocal relations in electrolyte solutions: II. Effect of ionic interactions on electroacoustic Title Onsager’s reciprocal relations in electrolyte solutions: II. Effect of ionic interactions on electroacoustic Author Gourdin-Bertin, S. Chassagne, C. Bernard, O. Jardat, M. Faculty Civil Engineering and Geosciences Department Hydraulic Engineering Date 2015-08-14 Abstract In electrolyte solutions, an electric potential difference, called the Ionic Vibration Potential (IVP), related to the ionic vibration intensity, is generated by the application of an acoustic wave. Several theories based on a mechanical framework have been proposed over the years to predict the IVP for high ionic strengths, in the case where interactions between ions have to be accounted for. In this paper, it is demonstrated that most of these theories are not consistent with Onsager’s reciprocal relations. A new expression for the IVP will be presented that does fulfill the Onsager’s reciprocal relations. We obtained this expression by deriving general expressions of the corrective forces describing non-ideal effects in electrolyte solutions. Subject hydrodynamicselectrolyteselectrostaticselectric currentselectric fields To reference this document use: http://resolver.tudelft.nl/uuid:1628cdcc-5c56-454f-ae71-f59f162c1497 Publisher American Institute of Physics ISSN 0021-9606 Source https://doi.org/10.1063/1.4927468 Source Journal of Chemical Physics, 143 (6), 2015 Part of collection Institutional Repository Document type journal article Rights © 2015 AIP Publishing Files PDF Chassagne_2015_.pdf 771.88 KB Close viewer /islandora/object/uuid:1628cdcc-5c56-454f-ae71-f59f162c1497/datastream/OBJ/view