Print Email Facebook Twitter Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid Title Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid Author Bavykina, A.V. (TU Delft ChemE/Catalysis Engineering) Rozhko, E. (TU Delft ChemE/Catalysis Engineering) Goesten, M.G. (TU Delft ChemE/Catalysis Engineering; Eindhoven University of Technology) Wezendonk, T.A. (TU Delft ChemE/Catalysis Engineering) Seoane, Beatriz (TU Delft ChemE/Catalysis Engineering) Kapteijn, F. (TU Delft ChemE/Catalysis Engineering) Makkee, M. (TU Delft ChemE/Catalysis Engineering) Gascon, Jorge (TU Delft ChemE/Catalysis Engineering) Date 2016-07-06 Abstract A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid. Subject carbon dioxide hydrogenationcatalyst shapingcovalent triazine frameworksformic acid To reference this document use: http://resolver.tudelft.nl/uuid:37ee796c-1685-4853-8cb8-8b692499f891 DOI https://doi.org/10.1002/cctc.201600419 Embargo date 2017-07-06 ISSN 1867-3880 Source ChemCatChem, 8 (13), 2217-2221 Bibliographical note Accepted Author Manuscript Part of collection Institutional Repository Document type journal article Rights © 2016 A.V. Bavykina, E. Rozhko, M.G. Goesten, T.A. Wezendonk, Beatriz Seoane, F. Kapteijn, M. Makkee, Jorge Gascon Files PDF Bavykina_et_al_revised.pdf 3.3 MB Close viewer /islandora/object/uuid:37ee796c-1685-4853-8cb8-8b692499f891/datastream/OBJ/view