Print Email Facebook Twitter Effect of cation rotation on charge dynamics in hybrid lead halide perovskites Title Effect of cation rotation on charge dynamics in hybrid lead halide perovskites Author Gelvez Rueda, M.C. (TU Delft ChemE/Opto-electronic Materials) Cao, Duyen H. (Northwestern University) Patwardhan, Sameer (Northwestern University) Renaud, N. (TU Delft ChemE/Opto-electronic Materials) Stoumpos, Constantinos C. (Northwestern University) Schatz, George C. (Northwestern University) Hupp, Joseph T. (Argonne National Laboratory; Northwestern University) Farha, Omar K. (King Abdulaziz University; Northwestern University) Savenije, T.J. (TU Delft ChemE/Opto-electronic Materials) Kanatzidis, Mercouri G. (Argonne National Laboratory; Northwestern University) Grozema, F.C. (TU Delft ChemE/Opto-electronic Materials) Date 2016-08-04 Abstract Organic-inorganic hybrid halide perovskites are a promising class of materials for photovoltaic application with reported power efficiencies over ∼22%. However, not much is known about the influence of the organic dipole rotation and phase transitions on charge carrier dynamics. Here, we report substantial changes in mobility and lifetime of charge carriers in CH3NH3PbI3 after the low-temperature tetragonal (β) to orthorhombic (γ) phase transition. By using microwave conductivity measurements, we observed that the mobility and lifetime of ionized charge carriers increase as the temperature decreases and a sudden increment is seen after the β-γ phase transition. For CH3NH3PbI3, the mobility and the half-lifetime increase by a factor of 3-6 compared with the values before the β-γ phase transition. We attribute the considerable change in the dynamics at low temperature to the decrease of the inherent dynamic disorder of the organic cation (CH3NH3 +) inside the perovskite crystal structure. To reference this document use: http://resolver.tudelft.nl/uuid:9292759e-cac7-4144-8ed6-8c128bc6d9a8 DOI https://doi.org/10.1021/acs.jpcc.6b06722 Embargo date 2017-07-11 ISSN 1932-7447 Source The Journal of Physical Chemistry C, 120 (30), 16577-16585 Part of collection Institutional Repository Document type journal article Rights © 2016 M.C. Gelvez Rueda, Duyen H. Cao, Sameer Patwardhan, N. Renaud, Constantinos C. Stoumpos, George C. Schatz, Joseph T. Hupp, Omar K. Farha, T.J. Savenije, Mercouri G. Kanatzidis, F.C. Grozema Files PDF Charge_DynamicsInHybridHa ... sV9_1_.pdf 1.62 MB Close viewer /islandora/object/uuid:9292759e-cac7-4144-8ed6-8c128bc6d9a8/datastream/OBJ/view